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Title: Kinetic Resolution of Primary Amines via Enantioselective N-Acylation with Acyl Chlorides in the Presence of Supramolecular Cyclodextrin Nanocapsules
Authors: Asahara, Haruyasu
Kida, Toshiyuki
Iwamoto, Takuya
Hinoue, Tomoaki
Akashi, Mitsuru
Issue Date: 2014
Publisher: Elsevier Ltd.
Journal Title: Tetrahedron
Volume: 70
Issue: 2
Start Page: 197
End Page: 203
Abstract: The non-enzymatic kinetic resolution of primary amines via enantioselective N-acylation with acyl chlorides was accomplished for the first time by using the selective sequestration of one enantiomer within a supramolecular cyclodextrin (CD) nanocapsule in nonpolar solvents. In addition, the first example of a crystalline structure for an inclusion complex between an acyl chloride and a CD derivative is reported.
DOI: 10.1016/j.tet.2013.11.097
Type: Journal Article
URI: http://hdl.handle.net/10173/1331
Appears in Collections:学術雑誌論文

Please use this identifier to cite or link to this item: http://hdl.handle.net/10173/1331

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